Hydrofluorocarbons have a clear effect on the ozone, which has recovered after they were replaced.
For the tiny man made portion of CO2 to drive the proven increase in atmospheric CO2, natural CO2 production and absorption have to be in perfect balance....then the man made portion, small as it is, accumulates. That's the global warming argument.
But another line of reasoning is CO2 is the dependent variable, driven by temperature which releases more of it.
Yet another argument is CO2 'sinks' will become more effective with more CO2 to absorb. So with an imbalance there might be a temporary increase in CO2, but as jungles grow and they are growing now, the CO2 will get absorbed and we reach a new balance. I like that theory because it seems so unlikely that you get perfect balance in the absence of a compensating mechanism
All interesting stuff, but we know so little. Here's another unknown factoid:
"If implemented, the Obama administration’s Climate Action Plan would reduce global temperatures by only 0.01, or one one-hundredth of a degree Celsius. President Obama’s former deputy secretary for Fossil Energy at the Department of Energy, Charles McConnell, said that the EPA’s carbon rules will have only a minor impact on global climate change. Yet regulations will cost billions of dollars and jeopardize thousands of jobs."
The Kyoto Treaty was also a bust, shifting the temperature curve by just 4 years at the end of the century, with a massive cost.
It's a complicated subject.